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Head-to-head record and recent meetings.
Last 10 meetings
| 15 Mar 26 | U0–1 | Bundesliga · Freiburg home | details → |
| 1 Nov 25 | D0–0 | Bundesliga · Union Berlin home | details → |
| 30 Mar 25 | U1–2 | Bundesliga · Freiburg home | details → |
| 8 Nov 24 | D0–0 | Bundesliga · Union Berlin home | details → |
| 18 May 24 | U1–2 | Bundesliga · Union Berlin home | details → |
| 13 Jan 24 | D0–0 | Bundesliga · Freiburg home | details → |
| 13 May 23 | U2–4 | Bundesliga · Union Berlin home | details → |
| 13 Nov 22 | F4–1 | Bundesliga · Freiburg home | details → |
| 7 May 22 | U1–4 | Bundesliga · Freiburg home | details → |
| 15 Dec 21 | D0–0 | Bundesliga · Union Berlin home | details → |
Scores shown from Freiburg's perspective. From graded matches on record.